2017. - V. 31. - N 12(193). - P. 51-53
A.D. Zubenko, A.I. Stankova, A.S. Oshchepkov, O.A. Fedorova,
Benzoazacrown compounds and their bifunctional derivatives were synthesized and features of their structure were determined by X-ray analyses. The proposed method is suitable for obtaining macrocycles with nitro- and ether groups into benzyl ring. To increase complex formation properties carboxyl and pyridine chelating groups were introduced in macrocycles. The results of X-ray analyses show the preorganization of synthesized benzoazacrown compounds for binding metal ion due to macrocyclic and chelating effect.
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