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UDK: 547.99

2016. - V. 30. - N 11(180). - P. 65-65

Olga Nikolaevna Rusina, Vera Andreevna Vil’, Alexander Olegovich Terent’ev,

OXIDATIVE C-O COUPLING OF DERIVATIVES OF β-DICARBONYL COMPOUNDS WITH MALONYL PEROXIDES

The possibility of selective functionalization of derivatives of β-dicarbonyl compounds with malonyl peroxides as oxidants was studied; reaction conditions were optimized. The influence of solvent, catalyst and reaction time on desired product yield was elucidated. In optimized reaction conditions the products of oxidative C-O coupling were obtained with 18-90 % yields.

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First page of the article:

РЕАКЦИИ ОКИСЛИТЕЛЬНОГО С-О СОЧЕТАНИЯ ПРОИЗВОДНЫХ β-ДИКАРБОНИЛЬНЫХ СОЕДИНЕНИЙ С МАЛОНИЛ ПЕРОКСИДАМИ

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Keywords

malonyl peroxide   oxidative C-O coupling   β-dicarbonyl compounds   β-дикарбонильные соединения   малонил пероксиды   реакции окислительного С-О сочетания  


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