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UDK: 547.495.1, 544.421.032.4, 544.431

2016. - V. 30. - N 11(180). - P. 58-59

Dmitry Vladimirovich Zimin, Dmitry Alekseevich Gordeev, Sergey Nikolaevich Mantrov,

KINETICS OF THE AMINOLYSIS OF ETHYLENE CARBONATE WITH n-BUTYLAMINE

Kinetics of the aminolysis of ethylene carbonate with n-butylamine in acetonitrile - ethylene carbonate (50% vol.) at 26.0-50.0 °C were studied. It is found that the reaction is complex and consists of two parallel reactions: amine-catalyzed and autocatalytic. Reactions rate constants were calculated.

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КИНЕТИЧЕСКИЕ ЗАКОНОМЕРНОСТИ АМИНОЛИЗА ЭТИЛЕНКАРБОНАТА АЛИФАТИЧЕСКИМИ АМИНАМИ НА ПРИМЕРЕ н-БУТИЛАМИНА

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Keywords

aminolysis   carbamates   ethylene carbonate   kinetics   n-butylamine   аминолиз   карбаматы   КИНЕТИКА   н-бутиламин   этиленкарбонат  


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