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UDK: 547.39

2016. - V. 30. - N 11(180). - P. 56-57

Oleg Vadimovich Bityukov, Vera Andreevna Vil’, Alina Olegovna Yarovaya, Alexander Olegovich Terent’ev,

OXIDATIVE С-Н FUNCTIONALIZATION OF β-DICARBONYL COMPOUNDS USING CATALYST SYSTEMS BASED ON NATURAL COMPOUNDS OF SILICON

Reaction of α-mono-substituted β-dicarbonyl compounds with cyclic diacyl peroxides catalyzed by silicon dioxide leads to the formation of products C-O oxidative coupling at α-position. Because of the unusual properties, cyclic diacyl peroxides can be used simultaneously as the oxidants and O-reagents. Selectively with yield from 67 to 93% coupling C-O products were prepared.

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First page of the article:

ОКИСЛИТЕЛЬНАЯ С-Н ФУНКЦИОНАЛИЗАЦИЯ β-ДИКАРБОНИЛЬНЫХ СОЕДИНЕНИЙ С ИСПОЛЬЗОВАНИЕМ КАТАЛИТИЧЕСКИХ СИСТЕМ НА ОСНОВЕ ПРИРОДНЫХ СОЕДИНЕНИЙ КРЕМНИЯ

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Keywords

peroxides   silicon compounds   β-dicarbonyl compounds   β-дикарбонильные соединения   пероксиды   соединения кремния  


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