2016. - V. 30. - N 11(180). - P. 56-57
Oleg Vadimovich Bityukov, Vera Andreevna Vil’, Alina Olegovna Yarovaya, Alexander Olegovich Terent’ev,
Reaction of α-mono-substituted β-dicarbonyl compounds with cyclic diacyl peroxides catalyzed by silicon dioxide leads to the formation of products C-O oxidative coupling at α-position. Because of the unusual properties, cyclic diacyl peroxides can be used simultaneously as the oxidants and O-reagents. Selectively with yield from 67 to 93% coupling C-O products were prepared.
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