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UDK: 541.133

2015. - V. 29. - N 1(160). - P. 34-36

Yuliya Mikhaylovna Artemkina, Ekaterina Nikolaevna Korotkova, Natalia Vladimirovna Plechkova, Kenneth Richard Seddon, Vitaliy Lukich Chumak, Vladimir Vasilyevitch Shcherbakov,

ASSOCIATION OF TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS{(TRIFLUOROMETHYL)SULFONYL}AMIDE IN DIMETHYLSULFOXIDE ACCORDING TO THE CONDUCTIVITY MEASUREMENTS

Specific conductivity of the diluted solutions of trihexyl(tetradecyl)phosphonium bis{(trifluoromethyl)sulfonyl}amide in dimethylsulfoxide (DMSO) have been measured in the 20 - 65 °C temperature range. By using conductometric data and the Lee-Wheaton equation, the thermodynamic parameters of association of the investigated ionic liquid have been calculated. It was established that with temperature increase, the association of the investigated electrolyte in DMSO also increases.

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АССОЦИАЦИЯ ТРИГЕКСИЛТЕТРАДЕЦИЛФОСФОНИЙ БИС{(ТРИФТОРМЕТИЛ) СУЛЬФОНИЛ}АМИДА В ДИМЕТИЛСУЛЬФОКСИДЕ ПО ДАННЫМ КОНДУКТОМЕТРИЧЕСКИХ ИЗМЕРЕНИЙ

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Keywords

association   conductivity   dimethylsulfoxide   trihexyl(tetradecyl)phosphonium bis{(trifluoromethyl)sulfonyl}amide   ассоциация   диметилсульфоксид   тригексилтетрадецилфосфоний бис{(трифторметил)сульфонил}амид   электропроводность  


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