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2014. - V. 28. - N 10(159). - P. 60-63

Tseimur Maulanavich Aliyeu, Daria Vladimirovna Berdnikova, Yuri Viktorovich Fedorov, Olga Anatol'evna Fedorova,

PHOTOCHEMICAL REACTIONS OF CROWN-CONTAINING STYRYLAZINES AND THEIR COMPLEXES WITH METAL CATIONS

A series of 15-crown-5-ether containing hetarylphenylethens was synthesized. Using UV and NMR spectroscopy the phototransformations of obtained compounds were studied. Irradiation of acetonitrile solutions of substrates with light with wavelength 365 nm lead to E-Z -isomerisation. Addition of Ba(ClO

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Keywords

E-Z-photoisomerization   E-Z-фотоизомеризация   hetarylphenylethenes   [2+2]-photocycloaddition   [2+2]-фотоциклоприсоединение   гетарилфенилэтены