2014. - V. 28. - N 10(159). - P. 24-28
Anton Dmitrievich Troynikov, Elena Raisovna Sabirzyanova,
Kinetic models for process of alkali-free demercaptanization in the presence of catalysts based on complexes of copper with quaternary ammonium bases, immobilized on various mineral carriers - perlkat silica gels and silochrome-120, are received. Activation parameters of process were determined. Dependence of catalyst efficiency on types of carrier and catalyst preparation methods is represented. It is established, that type of kinetic function is identical to the same active component of the catalyst; difference between reaction rate constants can be explained by distinction in catalyst preparation methods.
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