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UDK: 541.133

2014. - V. 28. - N 2(151). - P. 100-102

Yuliya Mikhaylovna Artemkina, Ekaterina Nikolaevna Korotkova, Natalia Vladimirovna Plechkova, Kenneth Richard Seddon, Vitaliy Lukich Chumak, Vladimir Vasilyevitch Shcherbakov,

ASSOCIATION OF TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS{(TRIFLUOROMETHYL)SULFONYL}AMIDE IN ACETONITRILE ACCORDING TO THE CONDUCTIVITY MEASUREMENTS

Specific conductances of the diluted solutions of trihexyl(tetradecyl)phosphonium bis{(trifluoromethyl)sulfonyl}amide in acetonitrile have been measured in the 20 - 65 °C temperature range. By using conductometric data and the Lee-Wheaton equation, the thermodynamic parameters of association of the investigated ionic liquid have been calculated. It was established that with temperature increase, the association of the investigated electrolyte in acetonitrile decreases.

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First page of the article:

АССОЦИАЦИЯ ТРИ-ГЕКСИЛТЕТРАДЕЦИЛФОСФОНИЙ БИС {(ТРИФТОРМЕТИЛ) СУЛЬФОНИЛ} АМИДА В АЦЕТОНИТРИЛЕ ПО ДАННЫМ КОНДУКТОМЕТРИЧЕСКИХ ИЗМЕРЕНИЙ

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Keywords

acetonitrile   association   conductivity   trihexyl(tetradecyl)phosphonium bis{(trifluoromethyl)sulfonyl}amide   ассоциация   ацетонитрил   три-гексилтетрадецилфосфоний бис {(трифторметил) сульфонил} амид   электропроводность  


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