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UDK: 544.542.2

2011. - V. 25. - N 12(128). - P. 104-110

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The combustion behavior of mixtures of ammonium perchlorate (AP) with a high content of ferrocenes and metal polyboride has been investigated. The dependence of burning rate on pressure for propellants containing various fractions of AP has been found to show a decreasу in the pressure exponent after a break, and the break shifts to high–pressure region when the AP particle size decreases. A mechanism has been proposed that implies the condensed-phase interaction of ferrocene with perchloric acid as the leading reaction of combustion. Thermocouple-aided study allowed us to estimate the depth of oxidation of metal poliboryde in the combustion wave.

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ЗАКОНОМЕРНОСТИ ГОРЕНИЯ ТОПЛИВНЫХ КОМПОЗИЦИЙ С НИЗКИМ СОДЕРЖАНИЕМ ОКИСЛИТЕЛЯ И ВЫСОКИМ СОДЕРЖАНИЕМ ФЕРРОЦЕНОВ

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