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UDK: 541.124

2011. - V. 25. - N 8(124). - P. 90-93

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On the basis of reference data the dependences of changes of standard energy of Gibbs formation of inorganic salts of metals with a various anion from a standard enthalpy of formation of these joints have been built. Within the series of compounds with the general anion and of equal valency the gained functions are presented by the linear equation y=ax+b, where a and b - empirical factors. The behaviour of empirical factors depending on valency of metal of salt is analysed. Values .fG0(298) for 75 connections of metals with valencies 1.5, absent in thermodynamic databases are calculated.

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ОБЩИЕ ЗАКОНОМЕРНОСТИ В ИЗМЕНЕНИИ СТАНДАРТНОЙ ЭНЕРГИИ ГИББСА ОБРАЗОВАНИЯ НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ

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